2,4,6-Tribromoaniline
Chemical compound
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Names | |||
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Preferred IUPAC name 2,4,6-Tribromoaniline | |||
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ECHA InfoCard | 100.005.183 | ||
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InChI
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Properties | |||
Chemical formula | C6H4Br3N | ||
Molar mass | 329.817 g·mol−1 | ||
Melting point | 120 °C (248 °F; 393 K) | ||
Boiling point | 300 °C (572 °F; 573 K) | ||
Solubility in water | Insoluble | ||
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Occupational safety and health (OHS/OSH): | |||
Main hazards | Harmful, Corrosive, Toxic | ||
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Danger | |||
Hazard statements | H301, H302, H311, H312, H315, H318, H319, H331, H332, H373 | ||
Precautionary statements | P260, P261, P264, P270, P271, P280, P301+P310, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P310, P311, P312, P314, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, P501 | ||
NFPA 704 (fire diamond) | 2 0 0 | ||
Flash point | Non-flammable | ||
Autoignition temperature | Non-flammable | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references |
Chemical compound
2,4,6-Tribromoaniline is a brominated derivative of aniline with the formula C6H4Br3N. It is used in organic synthesis of pharmaceuticals, agrochemicals and fire-extinguishing agents.[1]
Synthesis
2,4,6-Tribromoaniline can be prepared by treating bromine water with aniline in a solution of acetic acid or dilute hydrochloric acid:[1]
Reactions
Diazotization, then reaction with ethanol to replace the diazonium group with hydrogen, gives 1,3,5-tribromobenzene.[2]
See also
References
- ^ a b "Synthesis of 2,4,6-tribromoaniline from aniline".
- ^ Coleman, G. H.; Talbot, William F. (1933). "sym.-Tribromobenzene". Organic Syntheses. 13: 96. doi:10.15227/orgsyn.013.0096.